Get Advanced Organic Chemistry. Reactions and Synthesis PDF

By Carey F., Sundberg R.

ISBN-10: 0306462443

ISBN-13: 9780306462443

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Results from characterizations showed intimate association with the tubes and the bioactivity of the CNT–BSA conjugate was proven by a protein microdetection assay [125]. Research is under way to investigate the biocompatibility of chemically inert carbon nanotubes by immobilization of biopolymers and proteins at the tubes. The protein transferrin, tagged with a fluorescent label, was immobilized by covalent amide formation with CNT-COOHs in the presence of carbodiimide EDC and sulfoN-hydroxysuccinimide (sulfo-NHS) [127].

Theoretical first-principles total energy and electronic structure calculations of fully exohydrogenated zigzag and armchair SWCNTs (CnHn) point to crucial differences in the electronic and atomic structures with respect to hydrogen storage and device applications. CnHns were estimated to be stable up to a radius of a [8,8] CNT, with binding energies proportional to 1/r. By calculation, zigzag nanotubes were found to be more likely to be hydrogenated than armchair tubes with equal radius [147].

Amino-terminated DNA strands were used to functionalize the open ends and defect sites of oxidized SWCNTs [128]. 9 Schematic representation of the enhanced electrochemical detection of DNA hybridization based on an MWCNT-COOH constructed DNA biosensor. Haxani et al. reported carbodiimide-assisted amidation of SWCNT-COOHs with oligonucleotides and the preparation of a highly water-soluble adduct. Fluorescence imaging of individual nanotube bundles showed that the SWCNT–DNA adducts hybridized selectively with complementary strands [129].

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Advanced Organic Chemistry. Reactions and Synthesis by Carey F., Sundberg R.

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